1143571-24-7Relevant academic research and scientific papers
Stereoselective free-radical addition of secondary phosphine selenides to aromatic acetylenes
Trofimov, Boris A.,Gusarova, Nina K.,Arbuzova, Svetlana N.,Ivanova, Nina I.,Artem'ev, Alexander V.,Volkov, Pavel A.,Ushakov, Igor' A.,Malysheva, Svetlana F.,Kuimov, Vladimir A.
experimental part, p. 677 - 682 (2009/05/30)
Free-radical addition (AIBN, 65-70 °C, 5-7 h) of secondary phosphine selenides to arylacetylenes proceeds stereoselectively to give anti-Markovnikov adducts of predominantly Z-configuration (up to 97%) in 60-80% isolated yields, thus representing a rare e
