114403-39-3Relevant academic research and scientific papers
Supramolecular assemblies with symmetrical octahedral structures - Synthesis, characterization, and electrochemical properties
Jiang, Fei,Wang, Jun,Li, Jianzhong,Wang, Ning,Bao, Xichang,Wang, Ting,Yang, Ying,Lan, Zhenggang,Yang, Renqiang
, p. 375 - 380 (2013/03/14)
Functional nanosized cage complexes with an octahedral framework have been synthesized by the facile self-assembly reactions of six 90° Pd II-containing compounds {[Pd(dppf)(OTf)2] or [Pd(PPh 3)(OTf)2], dppf = 1
Direct observation of gold/palladium transmetalation in an organogold heck reaction
Roth, Katrina E.,Blum, Suzanne A.
, p. 4811 - 4813 (2011/11/05)
A new Heck-type reaction accessed the migratory insertion chemistry of palladium from organogold complexes. Observation, isolation, and characterization of a palladium intermediate established the role of gold/palladium transmetalation in this reaction. Recent reports of combining the reactivity of organogold compounds with palladium in organic synthesis generally assume a gold-to-palladium transmetalation step, although this step had not been directly observed in these reactions. The results herein furnish experimental evidence for the mechanisms of reactions mediated or catalyzed by both gold and palladium and reveal a migratory insertion strategy for outcompeting homocoupling pathways.
Trifluoromethanesulphonato-O Complexes of Platinum(II) and Palladium(II)
Diver, Catherine,Lawrence, Geoffrey A.
, p. 931 - 934 (2007/10/02)
Reaction of chloroplatinum(II) and chloropalladium(II) complexes containing amine, pyridine (py), or phosphine ligands at or above room temperature with anhydrous CF3SO3H leads to formation of trifluoromethanesulphonato-O complexes, characterized spectros
