114412-95-2

Basic information

• Product Name: (2S,3R,4S,6R)-acetic acid 4-azido-6-benzyloxy-2-methyltetrahydropyran-3-yl ester
• Synonyms: (2S,3R,4S,6R)-acetic acid 4-azido-6-benzyloxy-2-methyltetrahydropyran-3-yl ester
• CAS NO: 114412-95-2
• Molecular Weight: 305.334
• Mol File: 114412-95-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (2S,3R,4S,6R)-acetic acid 4-azido-6-benzyloxy-2-methyltetrahydropyran-3-yl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,3R,4S,6R)-acetic acid 4-azido-6-benzyloxy-2-methyltetrahydropyran-3-yl ester(114412-95-2)
• EPA Substance Registry System: (2S,3R,4S,6R)-acetic acid 4-azido-6-benzyloxy-2-methyltetrahydropyran-3-yl ester(114412-95-2)

Safety Data

• Hazardous Substances Data: 114412-95-2(Hazardous Substances Data)

Upstream product

• 34819-86-8 3,4-di-O-acetyl-6-deoxy-L-glucal 
• 114412-85-0 4-O-Acetyl-2,3,6-trideoxy-L-erythro-hex-2-enopyranose 
• 100-51-6 benzyl alcohol 

Downstream Products

• 114413-02-4 benzyl 3-azido-2,3,6-trideoxy-α-L-arabino-hexopyranoside 
• 114413-04-6 benzyl α-L-acosaminide 
• 890122-90-4 (2S,3R,4S,6R)-(6-benzyloxy-3-methoxy-2-methyltetrahydropyran-4-yl)methylcarbamic acid tert-butyl ester 
• 890122-89-1 (2S,3R,4S,6R)-(6-benzyloxy-3-methoxy-2-methyltetrahydropyran-4-yl)carbamic acid tert-butyl ester 
• 890122-88-0 (2S,3R,4S,6R)-4-azido-6-benzyloxy-3-methoxy-2-methyltetrahydropyran 
• 890123-65-6 (2S,3R,4S,6R)-6-Benzyloxy-3-methoxy-2-methyl-tetrahydro-pyran-4-ylamine 

Relevant articles and documents

Facile synthesis of C-aryl glycals from sugar-derived lactones

A general entry to C(1) aryl-substituted glycals from the corresponding sugar lactones is described. This approach features one-pot access to aryl glycals. A variety of aryllithium reagents can be used and the method is compatible with various 2-deoxysuga

Stereocontrolled Route to 3-Amino-2,3,6-trideoxy-hexopyranoses. K-10 Montmorillonite as a Glycosidation Reagent for Acosaminide Synthesis

A stereoselective synthesis of methyl .(or benzyl) 3-azido-2,3,6-trideoxy-α-L-arabino-hexopyranoside from di-O-acetyl-L-rhamnal is reported; it proceeds via addition of hydrazoic acid to a hex-2-enopyranose, followed by acetylation and glycosidation with