114418-35-8Relevant academic research and scientific papers
Diastereoselective addition of organomanganese compounds to α-alkoxysubstituted propanals
Kasatkin, A. N.,Biktimirov, R. Kh.,Podlipchuk, I. P.,Sultanmuratova, V. R.,Tolstikov, G. A.
, p. 161 - 165 (2007/10/02)
Reactions of organomanganese compounds R1MnI (R1 = Ph, 4-MeC6H4, Me, Bu, n-C7H15, BuCC, PhCC),prepared from R1Li and MnI2 in Et2O, with aldehydes MeCH(OR2)CHO (R2 = CH2Ph, CH2OMe, CH2OCH2Ph) afford threo-alcohols MeCH(OR2)CH(OH)R1 with high diastereoselec
STEREOCONTROLLED ONE-POT CONVERSIONS OF α-ALKOXY ESTERS TO SYN- AND ANTI-1,2-DIOL DERIVATIVES
Burke, Steven D.,Deaton, David N.,Olsen, Robert J.,Armistead, David M.,Blough, Bruce E.
, p. 3905 - 3906 (2007/10/02)
Complementary one-pot methods for the sequential addition of carbon and hydride nucleophiles to α-alkoxy esters leading to syn or anti mono-protected vicinal glycol derivatives are described.
ZnBr2-MEDIATED HIGHLY DIASTEREOSELECTIVE ADDITION OF GRIGNARD REAGENTS TO α-BENZYLOXY ALDEHYDES
Asami, Masatoshi,Kimura, Rieko
, p. 1221 - 1222 (2007/10/02)
α-Benzyloxy aldehydes reacted with Grignard reagents in the presence of ZnBr2 to afford vicinal syn-diol derivatives with high diastereoselectivity.
