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114420-33-6

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114420-33-6 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 114420-33-6 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,1,4,4,2 and 0 respectively; the second part has 2 digits, 3 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 114420-33:
(8*1)+(7*1)+(6*4)+(5*4)+(4*2)+(3*0)+(2*3)+(1*3)=76
76 % 10 = 6
So 114420-33-6 is a valid CAS Registry Number.

114420-33-6Downstream Products

114420-33-6Relevant articles and documents

Intermediate, synthesis and application of vaccine adjuvant MPLA

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Paragraph 0438-0440, (2021/10/27)

The invention discloses an intermediate of a vaccine adjuvant MPLA, and synthesis and application thereof. The intermediate provided by the invention takes the allyl phosphate ligand as MPLA phosphate group source, Nap is a protecting group, and can be conveniently removed in subsequent operation. The synthesized intermediate route is short, and the total yield is obviously increased. For synthesis and amplification MPLA, a foundation is provided.

Intermediate, synthesis and application of vaccine adjuvant MPLA

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Paragraph 0271-0273, (2021/10/27)

The invention discloses an intermediate of a vaccine adjuvant MPLA, and synthesis and application thereof. The intermediate provided by the invention takes the allyl phosphate ligand as MPLA phosphate group source, Nap is a protecting group, and can be conveniently removed in subsequent operation. The synthesized intermediate route is short, and the total yield is obviously increased. For synthesis and amplification MPLA, a foundation is provided.

A divergent synthesis of lipid A and its chemically stable unnatural analogues

Liu, Wen-Chi,Oikawa, Masato,Fukase, Koichi,Suda, Yasuo,Kusumoto, Shoichi

, p. 1377 - 1385 (2007/10/03)

Lipid A and its two chemically stable analogues, wherein the glycosidic phosphoryl groups in lipid A is replaced with 2-(phosphonooxy)ethyl or carboxymethyl groups, have been synthesized by an improved and divergent route via a common allyl glycoside intermediate in which the 4-hydroxy group was protected as a benzyl ether. The total yields were more than 20% for 11 or 12 steps starting from allyl 4,6-O-benzylidene-2-deoxy-2- (trichloroethoxycarbonylamino)-D-glucopyranoside. These synthetic chemically stable analogues induce interleukin-6 and tumor necrosis factor a in human peripheral whole blood cells with potencies comparable to those by natural- type synthetic lipid A. The Limulus activities of both analogues were found to be even stronger than the activity of the natural-type one.

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