114466-87-4 Usage
Physical appearance
White crystalline powder
Molecular weight
345.35 g/mol
Functional groups
Amine, Sulfonyl, Trifluoromethyl, and Phenyl groups
Uses
a. Versatile intermediate in the synthesis of pharmaceutical compounds and agrochemicals
b. Reagent in organic synthesis for carbon-carbon and carbon-nitrogen bond formation
c. Building block for a wide variety of organic substrates
d. Potential applications in the development of new drugs and agrochemicals
Reactivity
Can form various bonds and react with different functional groups
Stability
Stable under normal conditions, but may decompose upon exposure to heat or strong oxidizing agents
Solubility
Soluble in organic solvents like dichloromethane, ethyl acetate, and acetone
Boiling point
Not readily available, but expected to be relatively high due to the presence of multiple functional groups
Melting point
Not readily available, but expected to be relatively low due to the crystalline nature of the compound
Safety precautions
a. Handle with care, as it may be harmful if inhaled, ingested, or if it comes into contact with the skin
b. Use appropriate personal protective equipment (PPE) such as gloves, goggles, and lab coats when handling
c. Store in a cool, dry, and well-ventilated area, away from heat, sparks, and open flames
d. Dispose of according to local regulations and guidelines for hazardous materials
Check Digit Verification of cas no
The CAS Registry Mumber 114466-87-4 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,1,4,4,6 and 6 respectively; the second part has 2 digits, 8 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 114466-87:
(8*1)+(7*1)+(6*4)+(5*4)+(4*6)+(3*6)+(2*8)+(1*7)=124
124 % 10 = 4
So 114466-87-4 is a valid CAS Registry Number.
114466-87-4Relevant academic research and scientific papers
Structural Effects on the Transition States of Imine-Forming Eliminations in N-Substituted O-(Arylsulfonyl)hydroxylamines
Hoffman, Robert V.,Shankweiler, Jean M.
, p. 4019 - 4022 (2007/10/02)
A series of amines with various alkyl and aryl substituents at C-1 were converted to the corresponding N-(arylsulfonoxy)amines, which served as precursors for base-promoted, imine-forming elimination.By varying the bases used to promote the elimination and by varying the leaving groups attached to nitrogen, the Broensted parameters β and βlgCH3 were determined.These were used to locate the transition state on the More O'Ferrall-Jencks energy surface for elimination.Substituents were found to influence the structure of the activated complex markedly.Resonance effects were most important, while inductive effects had little influence .
