114467-07-1

Basic information

• Product Name: Benzenemethanamine, N-[[(4-nitrophenyl)sulfonyl]oxy]-3-(trifluoromethyl)-
• CAS NO: 114467-07-1
• Molecular Formula: C14H11F3N2O5S
• Molecular Weight: 376.313
• Mol File: 114467-07-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzenemethanamine, N-[[(4-nitrophenyl)sulfonyl]oxy]-3-(trifluoromethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanamine, N-[[(4-nitrophenyl)sulfonyl]oxy]-3-(trifluoromethyl)-(114467-07-1)
• EPA Substance Registry System: Benzenemethanamine, N-[[(4-nitrophenyl)sulfonyl]oxy]-3-(trifluoromethyl)-(114467-07-1)

Safety Data

• Hazardous Substances Data: 114467-07-1(Hazardous Substances Data)

Upstream product

• 2740-83-2 3-(TRIFLUOROMETHYL)BENZYLAMINE 
• 6209-72-9 4-nitrobenzenesulfonyl peroxide 

Downstream Products

• 138-42-1 p-nitrobenzenesulfonic acid 

Relevant articles and documents

Structural Effects on the Transition States of Imine-Forming Eliminations in N-Substituted O-(Arylsulfonyl)hydroxylamines

A series of amines with various alkyl and aryl substituents at C-1 were converted to the corresponding N-(arylsulfonoxy)amines, which served as precursors for base-promoted, imine-forming elimination.By varying the bases used to promote the elimination and by varying the leaving groups attached to nitrogen, the Broensted parameters β and βlgCH3 were determined.These were used to locate the transition state on the More O'Ferrall-Jencks energy surface for elimination.Substituents were found to influence the structure of the activated complex markedly.Resonance effects were most important, while inductive effects had little influence .