114469-01-1

Upstream product

• 114468-96-1 cis-1,3-dihydro-1-hydroxy-3-phenylnaphtho<1,2-c>furan 
• 292638-85-8 acrylic acid methyl ester 
• 100-58-3 phenylmagnesium bromide 
• 3378-82-3 1-bromo-2-naphthaldehyde 
• 114468-95-0 1-bromo-α-phenyl-2-naphthalenemethanol 

Relevant academic research and scientific papers

The Baylis-Hillman acetates in organic synthesis: Unprecedented sodium nitrite induced intramolecular Friedel-Crafts cyclization of secondary nitro compounds

Unprecedented sodium nitrite mediated intramolecular Friedel-Crafts cyclization of alkyl (E)-2-arylidene-4-nitroalkanoates and (E)-3-arylidene-5- nitroalkan-2-ones derived from Baylis-Hillman acetates, providing a facile protocol for synthesis of naphthal

2,3-Dichloro-5,6-dicyano-para-benzoquinone (DDQ)/methanesulfonic acid (MsOH)-mediated intramolecular arene-alkene oxidative coupling

An efficient intramolecular arene-alkene oxidative coupling of 1,4-diaryl-1,3-butadienes has been developed involving the use of a 2,3-dichloro-5,6-dicyano-para-benzoquinone (DDQ)/acid catalyst. The reaction involves the generation of a radical cation by abstraction of an electron from the substrate with DDQ, an intramolecular Friedel-Crafts-type reaction, and the loss of hydrogen radical.

1-Phenylisobenzofuran, 1-Phenylnaphthofuran, 1-Phenylnaphthofuran, and 3-Phenylnaphthofuran via Cyclic Hemiaminal, Hemiacetal, and Acetal Precursors

The title compounds have been generated via cyclic hemiaminal, hemiacetal, and acetal precursors and trapped in Diels-Alder reactions with several dienophiles.The precursors are easily prepared from o-bromobenzyl alcohol, 2-bromo-3-naphthalenemethanol, or