114474-06-5Relevant academic research and scientific papers
Fluoride Ion Promoted Reactions of α-Halo Silanes: Synthesis of Stilbenes, Epoxides, Cyclopropanes, Benzazepines, and Phthalidylisoquinolines
Kessar, Satinder V.,Singh, Paramjit,Kaur, Nachhattar Pal,Chawla, Usha,Shukla, Kalpana,et al.
, p. 3908 - 3912 (2007/10/02)
Reaction of α-halo silanes 1 with CsF in DMF affords stilbenes 5.In the presence of added aldehydes, epoxides 6 are obtained, while with electron-deficient olefins the corresponding cyclopropanes 7 are formed.A similar reaction of 1a with iminium compounds 8 in HMPA leads to 2-phenyl-3-benzazepines 12, whereas 1b or 17 furnishes phthalidylisoquinolines 15.
Fluoride Ion Initiated Reactions of α-Halosilanes; Facile Synthesis of Some Stilbenes, Epoxides and Cyclopropanes
Kessar, Satinder V.,Singh, Paramjit,Venugopal, D.
, p. 605 - 606 (2007/10/02)
Treatment of α-halosilanes (1) with CsF in DMF furnishes stilbenes (3); in the presence of added aldehydes epoxides (5) are obtained while with electron deficient olefins the corresponding cyclopropanes (6) are formed.
