114501-79-0Relevant academic research and scientific papers
1-METHOXY-1-(PHENYLTHIO)CYCLOPROPANES FROM OLEFINS VIA THE PUMMERER REARRANGEMENT
Bhupathy, M.,Cohen, Theodore
, p. 4797 - 4800 (2007/10/02)
The Pummerer rearrangements of cyclopropyl(methoxy)phenylsulfonium salts proceed via sulfur-stabilized carbocations to yield the title compounds.The sulfonium salts were prepared in high yields from olefins via carbene addition, oxidation, and methylation
1-PHENYLTHIO-1-(TRIMETHYLSILOXY)CYCLOPROPANES VIA THE SILA-PUMMERER REARRANGEMENT
Bhupathy, M.,Cohen, Theodore
, p. 4793 - 4796 (2007/10/02)
This first study of the sila-Pummerer rearrangement in a cyclopropane system reveals that several 1-trimethylsiloxy-1-(phenylthio)cyclopropanes can be prepared stereoselectively through putative sulfur-stabilized carbocationic intermediates.
