114523-01-2Relevant academic research and scientific papers
UNEXPECTED REACTIONS OF 1,4-DIAZA-1,3-DIENES UNDER ACYLATING CONDITIONS. A NEW CYCLIZATION TO NON-ACYLATED IMIDAZOLE DERIVATIVES
Armesto, Diego,Bosch, Paula,Horspool, William M.,Ortiz, Maria J.
, p. 4605 - 4608 (1987)
The reaction of anions from 1,2-bisimines with acid chlorides gives unacylated 2H-imidazoles.The unprecedented reactivity of these anions is interpreted by cyclization of the radical generated by electron transfer from the anion to the acid chloride.
