114527-25-2

Basic information

• Product Name: Zn⁽²⁺⁾*C₆H₂(NO₂)2(O)CO₂^(2-)=ZnC₆H₂(NO₂)2(O)CO₂
• CAS NO: 114527-25-2
• Molecular Weight: 291.492
• Mol File: 114527-25-2.mol

Chemical Properties

• CAS DataBase Reference: Zn⁽²⁺⁾*C₆H₂(NO₂)2(O)CO₂^(2-)=ZnC₆H₂(NO₂)2(O)CO₂(CAS DataBase Reference)
• NIST Chemistry Reference: Zn⁽²⁺⁾*C₆H₂(NO₂)2(O)CO₂^(2-)=ZnC₆H₂(NO₂)2(O)CO₂(114527-25-2)
• EPA Substance Registry System: Zn⁽²⁺⁾*C₆H₂(NO₂)2(O)CO₂^(2-)=ZnC₆H₂(NO₂)2(O)CO₂(114527-25-2)

Safety Data

• Hazardous Substances Data: 114527-25-2(Hazardous Substances Data)

Upstream product

• 609-99-4 3,5-dinitrosalicylic acid 
• 19229-79-9 zinc(II) cation 

Relevant articles and documents

Effects of Intramolecular Hydrogen Bonding on the Rates of Complex Formation of Co2+ and Zn2+ with Substituted Salicylic Acids

The kinetics of the complex formation of Co2+ and Zn2+ with two substituted salycilates have been investigated and compared to those of Ni2+ (reported previously).The rate constants for the unprotonated salicylates are consistent with a rate-determining first substitution step at the respective aquometal ion.Because of strong intramolecular hydrogen bonding, the monoprotonated ligands are much less reactive (80-4000-fold).The metal ion dependence of the rate constants for these species leads to the conclusion that in the rections involving Ni2+ and Co2+ ring closure is rate determining, whereas in case of the very labile Zn(II) the opening of the internal H bond in the initial complex becames rate determining.