114534-30-4

Upstream product

• 109-72-8 n-butyllithium 
• 23438-23-5 4-hydroxy-4-methyl-cyclohexa-2,5-dienone 
• 42860-78-6 4-butyl-4-hydroxy-cyclohexa-2,5-dienone 
• 917-54-4 methyllithium 

Downstream Products

• 17269-95-3 4-Butyl-2-methylphenol 
• 6891-45-8 2-Butyl-4-methylphenol 

Relevant academic research and scientific papers

REACTIONS OF ORGANOLITHIUM REAGENTS WITH p-BENZOQUINONES AND CYCLOHEXADIENONS, SYNTHESIS OF 4-ALKYL-4-HYDROXYCYCLOHEXA-2,5-DIEN-1-ONES AND 1,4-DIALKYLCYCLOHEXA-2,5-DIENE-1,4-DIOLS.

Addition of organolithium reagents to p-benzoquinones in ether gives the corresponding 4-alkyl-4-hydroxycyclohexa-2,5-dien-1-ones.Addition of excess of the reagent to the p-benzoquinones, or to the 4-alkyl-4-hydroxycyclohexa-3,5-dien-1-ones, in tetrahydrofuran, gives the corresponding dialkylcyclohexa-2,5-diene-1,4-diols.