114544-16-0Relevant academic research and scientific papers
Saturated nitrogen-containing heterocycles. 19. Catalytic reduction of 10- and 9,10-substituted sym-octahydroacridinium salts
Seller,Reshetov,Seller,Kriven'ko
, p. 971 - 974 (2007/10/03)
10-Methyl(phenyl)- and 9,10-diphenylperhydroacridines have been obtained by the catalytic reduction of 10- and 9,10-substituted sym-octahydroacridinium salts. Selective reduction of the furan ring occurred in the case of 9-(2-furyl)-10-phenyl-sym-octahydroacridinium perchlorate. The stereoisomeric composition of the reaction products has been established and a probable scheme for their formation has been proposed.
SATURATED NITROGEN-CONTAINING HETEROCYCLES. 16. CATALYTIC SYNTHESIS OF N-ARYLPERHYDROACRIDINES
Nikolaeva, T. G.,Yudovich, L. M.,Komyagin, N. T.,Yanovskii, A. I.,Struchkov, Yu. T.,Kriven'ko, A. P.
, p. 932 - 937 (2007/10/02)
Catalytic hydrogenation of methylene-2,2'-dicyclohexanone in the presence of substituted anilines or nitrobenzenes involves the formation of N-arylperhydroacridines. The stereoisomeric composition and yields of the latter are determined by the nature and
SATURATED NITROGEN-CONTAINING HETEROCYCLES. 13. PERHYDROACRIDINES. SYNTHESIS AND STEREOCHEMISTRY
Kriven'ko, A. P.,Nikolaeva, T. G.,Yudovich, L. M.,Komyagin, N. T.,Yanovskii, A. I.,et al.
, p. 1324 - 1329 (2007/10/02)
The configurations of the perhydroacridines formed in the catalytic hydroamination of threo-methylenedicyclohexanone and the product of its cyclization - 2-hydroxy-2,3-tetramethylenebicyclononan-9-one - were established by means of the 13C NMR spectra and alternative synthesis.It is shown that isomers with cis-anti-cis and cis-syn-cis configurations are formed as a result of the reactions.The results of X-ray diffraction analysis are presented for cis-syn-cis-N-(2-hydroxyethyl)perhydroacridine.
