114566-79-9Relevant academic research and scientific papers
Et3B Induced Stereoselective Radical Addition of Ph3GeH to Carbon-Carbon Multiple Bonds and Its Application to Isomerization of Olefins
Nozaki, Kyoko,Ichinose, Yoshifumi,Wakamatsu, Kuni,Oshima, Kichiro,Utimoto, Kiitiro
, p. 2268 - 2272 (2007/10/02)
Triphenylgermane easily adds to acetylenes or terminal olefines in the presence of Et3B to give alkenyltriphenylgermane or alkyltriphenylgermane respectively under excellent control of regio- and stereoselectivities.While Et3B catalyzed addition of Ph3GeH
Palladium Catalyzed Hydrostannylation and Hydrogermylation of Acetylenes
Ichinose, Yoshifumi,Oda, Hiroji,Oshima, Koichiro,Utimoto, Kiitiro
, p. 3468 - 3470 (2007/10/02)
Treatment of acetylenes with Ph3SnH or Ph3GeH in the presence of a catalytic amount of Pd(PPh3)4 provides the corresponding alkenyltriphenylstannanes or alkenyltriphenylgermanes in good yields.
ET3B Induced Stereoselective Radical Addition of Ph3GeH to Acetylenes and its Application to Isomerization of Olefins
Ichinose, Yoshifumi,Nozaki, Kyoko,Wakamatsu, Kuni,Oshima, Koichiro,Utimoto, Kiitiro
, p. 3709 - 3712 (2007/10/02)
Triphenylgermane adds easily to acetylenes in the presence of Et3B to give (E)- or (Z)-alkenyltriphenylgermanes, respectively, under excellent control of regio- and stereoselectivities.
