114566-79-9Relevant academic research and scientific papers
Et3B Induced Stereoselective Radical Addition of Ph3GeH to Carbon-Carbon Multiple Bonds and Its Application to Isomerization of Olefins
Nozaki, Kyoko,Ichinose, Yoshifumi,Wakamatsu, Kuni,Oshima, Kichiro,Utimoto, Kiitiro
, p. 2268 - 2272 (2007/10/02)
Triphenylgermane easily adds to acetylenes or terminal olefines in the presence of Et3B to give alkenyltriphenylgermane or alkyltriphenylgermane respectively under excellent control of regio- and stereoselectivities.While Et3B catalyzed addition of Ph3GeH
ET3B Induced Stereoselective Radical Addition of Ph3GeH to Acetylenes and its Application to Isomerization of Olefins
Ichinose, Yoshifumi,Nozaki, Kyoko,Wakamatsu, Kuni,Oshima, Koichiro,Utimoto, Kiitiro
, p. 3709 - 3712 (2007/10/02)
Triphenylgermane adds easily to acetylenes in the presence of Et3B to give (E)- or (Z)-alkenyltriphenylgermanes, respectively, under excellent control of regio- and stereoselectivities.
Palladium Catalyzed Hydrostannylation and Hydrogermylation of Acetylenes
Ichinose, Yoshifumi,Oda, Hiroji,Oshima, Koichiro,Utimoto, Kiitiro
, p. 3468 - 3470 (2007/10/02)
Treatment of acetylenes with Ph3SnH or Ph3GeH in the presence of a catalytic amount of Pd(PPh3)4 provides the corresponding alkenyltriphenylstannanes or alkenyltriphenylgermanes in good yields.
