1145681-45-3Relevant academic research and scientific papers
Thermal intramolecular [2 + 2] cycloaddition: Synthesis of 3-azabicyclo[3.1.1]heptanes from morita-baylis-hillman adduct-derived 4,4-diaryl-1,3-dienes
Kim, Ko Hoon,Lim, Jin Woo,Lee, Junseung,Go, Min Jeong,Kima, Jae Nyoung
supporting information, p. 3363 - 3369 (2015/02/02)
Various 3-azabicyclo[3.1.1]heptane derivatives were synthesized from Morita-Baylis-Hillman adduct-derived 1,3-dienes bearing a 4,4-diaryl moiety through a thermal intramolecular [2+2] cycloaddition approach. By using the same approach, bicyclo[3.1.1]heptane, 3-azabicyclo[3.2.0]heptane, and 3-oxabicyclo[3.1.1]heptane derivatives could also be synthesized. A structurally similar dimethyl-Gallyl derivative underwent an intramolecular ene reaction to afford the pyrrolidine derivative.
Palladium-catalyzed synthesis of indane and cyclobuta[a]indenes from homoallylic alcohols derived from Baylis-Hillman adducts: Base-dependent stereoselectivity for the benzylidene group in cyclobuta[a]indene
Kim, Ko Hoon,Kim, Se Hee,Park, Sunhong,Kim, Jae Nyoung
supporting information; experimental part, p. 3328 - 3336 (2011/06/11)
Various indane and cyclobuta[a]indene derivatives were synthesized by palladium-catalyzed cyclization of homoallylic alcohol derivatives prepared from Baylis-Hillman adducts. Especially, cyclobuta[a]indene derivative was synthesized stereoselectively by p
Anti-selective epoxidation of methyl α-methylene-β-tert- butyldimethylsilyloxycarboxylate esters. evidence for stereospecific oxygen atom transfer in a nucleophilic epoxidation Process
Svenda, Jakub,Myers, Andrew G.
supporting information; experimental part, p. 2437 - 2440 (2009/11/30)
Methyl r-methylene-β-tert-butyldimethylsilyloxycarboxylate esters are found to undergo diastereoselective epoxidation in the presence of potassium tert-butoxide-tert-butyl hydroperoxide to form anti products. In an effort to better understand mechanistic
