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1146219-08-0

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1146219-08-0 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 1146219-08-0 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,1,4,6,2,1 and 9 respectively; the second part has 2 digits, 0 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 1146219-08:
(9*1)+(8*1)+(7*4)+(6*6)+(5*2)+(4*1)+(3*9)+(2*0)+(1*8)=130
130 % 10 = 0
So 1146219-08-0 is a valid CAS Registry Number.

1146219-08-0Downstream Products

1146219-08-0Relevant articles and documents

Chemoselective dehydrogenative esterification of aldehydes and alcohols with a dimeric rhodium(II) catalyst

Cheng, Junjie,Zhu, Meijuan,Wang, Chao,Li, Junjun,Jiang, Xue,Wei, Yawen,Tang, Weijun,Xue, Dong,Xiao, Jianliang

, p. 4428 - 4434 (2016)

Dehydrogenative cross-coupling of aldehydes with alcohols as well as dehydrogentive cross-coupling of primary alcohols to produce esters have been developed using a Rh-terpyridine catalyst. The catalyst demonstrates broad substrate scope and good functional group tolerance, affording esters highly selectively. The high chemoselectivity of the catalyst stems from its preference for dehydrogenation of benzylic alcohols over aliphatic ones. Preliminary mechanistic studies suggest that the active catalyst is a dimeric Rh(ii) species, operating via a mechanism involving metal-base-metal cooperativity.

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