114644-34-7Relevant academic research and scientific papers
UNUSUAL CONJUGATE ADDITION OF ORGANOLITHIUM REAGENT TO α,β-UNSATURATED KETONE
Maruoka, Keiji,Nonoshita, Katsumasa,Yamamoto, Hisashi
, p. 5723 - 5726 (2007/10/02)
The conjugate addition of organolithium reagent to α,β-unsaturated ketone has been accomplished with methylaluminum bis(2,6-di-tert-butyl-4-alkylphenoxide) (MAD and MAT).Here combination of alkyllithium and MAD (or MAT) constitutes an amphiphilic system that allows to exhibit unusual selectivity in the alkylation of enones with alkyllithium.
