114671-90-8 Usage
Structure
Cyclobutanecarboxylic acid derivative with a hydroxymethyl group attached to the carbon atom
Functional groups
Carboxylic acid (-COOH), hydroxymethyl (-CH2OH)
Appearance
Unknown, but likely a solid or liquid depending on the conditions
Solubility
Unknown, but likely soluble in organic solvents like ethanol or methanol due to the presence of the hydroxymethyl group
Stability
Stable under normal conditions, but may decompose under extreme temperatures or in the presence of strong oxidizing agents
Reactivity
Reacts with various reagents to form different chemical compounds, making it versatile in organic chemistry
Applications
Used in the synthesis of pharmaceuticals, agrochemicals, and as a building block in organic chemistry
Research and industrial use
Commonly used in research and industrial applications due to its versatility and ability to create various other chemicals and compounds
Safety
Unknown, but should be handled with care due to its reactivity and potential use in pharmaceutical and agrochemical synthesis
Check Digit Verification of cas no
The CAS Registry Mumber 114671-90-8 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,1,4,6,7 and 1 respectively; the second part has 2 digits, 9 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 114671-90:
(8*1)+(7*1)+(6*4)+(5*6)+(4*7)+(3*1)+(2*9)+(1*0)=118
118 % 10 = 8
So 114671-90-8 is a valid CAS Registry Number.
114671-90-8Relevant articles and documents
Palladium(II)-catalyzed enantioselective C(sp3)-H activation using a chiral hydroxamic acid ligand
Xiao, Kai-Jiong,Lin, David W.,Miura, Motofumi,Zhu, Ru-Yi,Gong, Wei,Wasa, Masayuki,Yu, Jin-Quan
supporting information, p. 8138 - 8142 (2014/06/23)
An enantioselective method for Pd(II)-catalyzed cross-coupling of methylene β-C(sp3)-H bonds in cyclobutanecarboxylic acid derivatives with arylboron reagents is described. High yields and enantioselectivities were achieved through the development of chiral mono-N-protected α-amino-O- methylhydroxamic acid (MPAHA) ligands, which form a chiral complex with the Pd(II) center. This reaction provides an alternative approach to the enantioselective synthesis of cyclobutanecarboxylates containing α-chiral quaternary stereocenters. This new class of chiral catalysts also show promises for enantioselective β-C(sp3)-H activation of acyclic amides.
