1147459-46-8

Basic information

• Product Name: (E)-2-(2-(4'-methylbiphenyl-4-yl)vinyl)-2,3-dihydro-1H-naphtho[1,8-de][1,3,2]diazaborinine
• Synonyms: (E)-2-(2-(4'-methylbiphenyl-4-yl)vinyl)-2,3-dihydro-1H-naphtho[1,8-de][1,3,2]diazaborinine
• CAS NO: 1147459-46-8
• Molecular Weight: 360.266
• Mol File: 1147459-46-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (E)-2-(2-(4'-methylbiphenyl-4-yl)vinyl)-2,3-dihydro-1H-naphtho[1,8-de][1,3,2]diazaborinine(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-2-(2-(4'-methylbiphenyl-4-yl)vinyl)-2,3-dihydro-1H-naphtho[1,8-de][1,3,2]diazaborinine(1147459-46-8)
• EPA Substance Registry System: (E)-2-(2-(4'-methylbiphenyl-4-yl)vinyl)-2,3-dihydro-1H-naphtho[1,8-de][1,3,2]diazaborinine(1147459-46-8)

Safety Data

• Hazardous Substances Data: 1147459-46-8(Hazardous Substances Data)

Upstream product

• 5656-71-3 2,3-dihydro-1H-naphtho[1,8-de][1,3,2]diazaborinine 
• 870004-04-9 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)styrene 
• 1073-67-2 4-vinylbenzyl chloride 
• 1245706-92-6 (E)-2-(4-chlorostyryl)-2,3-dihydro-1H-naphtho[1,8-de][1,3,2]diazaborinine 
• 5720-05-8 4-methylphenylboronic acid 
• 106-38-7 para-bromotoluene 
• 1245706-97-1 (E)-2-(4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)styryl)-2,3-dihydro-1H-naphtho[1,8-de][1,3,2]diazaborinine 
• 1147459-31-1 (E)-2-(4-bromostyryl)-2,3-dihydro-1H-naphtho[1,8-de][1,3,2]diazaborinine 

Downstream Products

• 1147459-58-2 C₁₅H₁₅BO₂ 

Relevant articles and documents

Rhodium-catalyzed dehydroborylation of styrenes with Naphthalene-1,8- diaminatoborane [(dan)BH]: New synthesis of masked β-borylstyrenes as new phenylene-vinylene cross-coupling modules

Styrene derivatives underwent dehydroborylation with naphthalene-1,8- diaminatoborane [(dan)BH] in the presence of a cationic rhodium complex, giving β-borylstyrene derivatives in good yields. Thus prepared β-borylstyrenes bearing a chlorine or B(pin) group on their aromatic rings were utilized for the synthesis of highly conjugated molecules through stepwise cross-coupling, taking advantage of the dan group as an effective protective group for a boronyl group.