1148044-85-2

Upstream product

• 56377-46-9 S-Benzyl-2-bromthioacetat 
• 158388-66-0 Br^(1-)*C₂₇H₂₄OPS⁽¹⁺⁾ 
• 603-35-0 triphenylphosphine 

Downstream Products

• 1376702-20-3 (E)-S-benzyl 4-hydroxybut-2-enethioate 
• 1376702-28-1 S-benzyl 2-(2-cyclohexyl-1,3-dioxolan-4-yl)ethanethioate 
• 1376702-27-0 S-benzyl 2-(2-cyclohexyl-1,3-dioxolan-4-yl)ethanethioate 

Relevant academic research and scientific papers

Thioallenoates in catalytic enantioselective [2+2]-cycloadditions with unactivated alkenes

The application of thioallenoates to catalytic enantioselective [2+2]-cycloadditions with unactivated alkenes is reported. In many cases, the thioallenoates examined exhibit superior reactivity and selectivity compared to the allenic esters generally used in these cycloadditions.

Asymmetric isomerization of ω-hydroxy-α,β-unsaturated thioesters into β-mercaptolactones by a bifunctional aminothiourea catalyst

We present a novel methodology for the asymmetric synthesis of β-mercaptolactones via isomerization of ω-hydroxy-α,β- unsaturated thioesters by means of a bifunctional aminothiourea catalyst. The catalyst interacts with the substrate through the cooperati

Organocatalytic asymmetric oxy-Michael addition to a γ-hydroxy- α,β-unsaturated thioester via hemiacetal intermediates

We report an asymmetric oxy-Michael addition to a γ-hydroxy-α, β-unsaturated thioester via hemiacetal intermediates in the presence of Cinchona-alkaloid-thiourea-based bifunctional organocatalysts. This method provides a novel enantioselective route to β-hydroxy carboxyl compounds, which in turn can be used to synthesize valuable chiral building blocks.