114835-74-4Relevant academic research and scientific papers
THE PREPARATION OF A NEW SERIES OF BRIDGED TRINUCLEAR COMPLEXES BY REACTION OF η5-(C5H4Li) COMPOUNDS WITH ALKYLTRICHLOROSILANES
Wright, Michael E.,Day, Victor W.
, p. 43 - 50 (2007/10/02)
Several new bridged trinuclear complexes of the general formula RSi5-C5H4M(CO)nR1>3, have been prepared in good yield from the reaction of the lithiated compounds (η5-C5H4Li)M(CO)nR1 (M = Mn, W, Fe; R1 = Me, Et, and benzyl) with various alkyl trichlorosilanes.The crystal and molecular structure of MeSi5-C5H4Fe(CO)2C2H5>3 is presented.In addition, some limitations of the direct cyclopentadienyl ring metalation are discussed.
