114853-42-8Relevant articles and documents
Regulating Cofactor Balance In Vivo with a Synthetic Flavin Analogue
Tan, Zhuotao,Zhu, Chenjie,Fu, Jingwen,Zhang, Xiaowang,Li, Ming,Zhuang, Wei,Ying, Hanjie
supporting information, p. 16464 - 16468 (2018/11/23)
A novel strategy to regulate cofactor balance in vivo for whole-cell biotransformation using a synthetic flavin analogue is reported. High efficiency, easy operation, and good applicability were observed for this system. Confocal laser scanning microscopy was employed to verify that the synthetic flavin analogue can directly permeate into Escherichia coli cells without modifying the cell membrane. This work provides a promising intracellular redox regulatory approach to construct more efficient cell factories.
Chemoselective sulfide oxidation mediated by bridged flavinium organocatalysts
Marsh, Barrie J.,Carbery, David R.
scheme or table, p. 2362 - 2365 (2010/05/19)
The chemoselective oxidation of sulfides to sulfoxides, catalysed by bridged, tetracyclic flavinium catalysts is presented. The flavinium catalysts are easily prepared via a telescoped three-step process. A range of sulfoxides is accessed in excellent yield and chemoselectivity.