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114873-01-7

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114873-01-7 Usage

Chemical Properties

off-white crystalline powder

Check Digit Verification of cas no

The CAS Registry Mumber 114873-01-7 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,1,4,8,7 and 3 respectively; the second part has 2 digits, 0 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 114873-01:
(8*1)+(7*1)+(6*4)+(5*8)+(4*7)+(3*3)+(2*0)+(1*1)=117
117 % 10 = 7
So 114873-01-7 is a valid CAS Registry Number.
InChI:InChI=1/C14H18FNO4/c1-14(2,3)20-13(19)16-11(12(17)18)8-9-5-4-6-10(15)7-9/h4-7,11H,8H2,1-3H3,(H,16,19)(H,17,18)/t11-/m1/s1

114873-01-7 Well-known Company Product Price

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  • TCI America

  • (B4367)  N-(tert-Butoxycarbonyl)-3-fluoro-L-phenylalanine  >98.0%(HPLC)(T)

  • 114873-01-7

  • 1g

  • 690.00CNY

  • Detail
  • TCI America

  • (B4367)  N-(tert-Butoxycarbonyl)-3-fluoro-L-phenylalanine  >98.0%(HPLC)(T)

  • 114873-01-7

  • 5g

  • 2,350.00CNY

  • Detail
  • Alfa Aesar

  • (H51988)  N-Boc-3-fluoro-L-phenylalanine, 95%   

  • 114873-01-7

  • 250mg

  • 265.0CNY

  • Detail
  • Alfa Aesar

  • (H51988)  N-Boc-3-fluoro-L-phenylalanine, 95%   

  • 114873-01-7

  • 1g

  • 706.0CNY

  • Detail
  • Alfa Aesar

  • (H51988)  N-Boc-3-fluoro-L-phenylalanine, 95%   

  • 114873-01-7

  • 5g

  • 2646.0CNY

  • Detail
  • Aldrich

  • (14996)  Boc-Phe(3-F)-OH  ≥98.0% (TLC)

  • 114873-01-7

  • 14996-5G

  • 4,924.53CNY

  • Detail

114873-01-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name Boc-3-fluoro-L-phenylalanine

1.2 Other means of identification

Product number -
Other names (S)-2-((tert-Butoxycarbonyl)amino)-3-(3-fluorophenyl)propanoic acid

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:114873-01-7 SDS

114873-01-7Relevant articles and documents

New reagent for the introduction of Boc protecting group to amines: Boc-OASUD

Maheswara Rao, B. Leela,Nowshuddin, Shaik,Jha, Anjali,Divi, Murali K.,Rao

, p. 2127 - 2132 (2017)

A new reagent, tert-butyl (2,4-dioxo-3-azaspiro [5,5] undecan-3-yl) carbonate (Boc-OASUD) for the preparation of N-Boc-amino acids is described. The Boc-OASUD reacts with amino acids and their esters at room temperature in the presence of a base and gives N-Boc-amino acids and their esters in good yields and purity. Introduction of the Boc group takes place without racemization. The Boc-OASUD, being a solid and more stable, is a better alternative to di-tert-butyl dicarbonate which is low melting and has to be dispensed in plastic containers than glass because of its poor stability.

OPIOID RECEPTOR MODULATORS AND PRODUCTS AND METHODS RELATED THERETO

-

Page/Page column 110, (2019/10/29)

Compounds are provided having the structure of Formula (I): or a pharmaceutically acceptable isomer, racemate, hydrate, solvate, isotope, or salt thereof, wherein A, B, L, R3, R4, R5, R6, R8, m and n are as defined herein. Such compounds modulate the opioid receptor, particulare the mu-opioid receptor (MOR) and/or the kappa-opioid receptor (KOR), and/or the delta-opioid receptor (DOR). Products containing such compounds, as well as methods for their use and preparation, are also provided.

Studies of Neurokinin Antagonists. 4. Synthesis and Structure-Activity Relationships of Novel Dipeptide Substance P Antagonists: N2--L-prolyl>-N-methyl-N-(phenylmethyl)-3-(2-naphthyl)-L-alaninamide and Its Related Compounds

Hagiwara, Daijiro,Miyake, Hiroshi,Igari, Norihiro,Karino, Masako,Maeda, Yasue,et al.

, p. 2090 - 2099 (2007/10/02)

As an extension of our studies on discovering a novel substance P (SP) antagonist, we modified the previously reported dipeptide, N2-2-(1H-indol-3-ylcarbonyl)-L-lysyl>-N-methyl-N-(phenylmethyl)-L-phenylalaninamide (2b).The lysine part in 2b was first optimized to a (2S,4R)-hydroxyproline derivative (3h), which is 2-fold more potent than 2b in SP binding assay using guinea pig lung membranes.Next we modified the 1H-indol-3-ylcarbonyl part in 3h.Introduction of a methyl group at the indole nitrogen enhanced the oral activity, while retaining the binding activity.Finally, we modified the phenylalanine part to culminate in the most potent compound 7k (FK888), which is a potent SP antagonist with NK1 selectivity as well as oral activity.

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