114907-08-3Relevant academic research and scientific papers
Polyphosphate Ester-catalysed Cyclodehydration of Monoesters of N-Substituted 3-(Indol-3'-yl)-5-methylcyclohex-4-ene-1,2-dicarboxylic Acids; Stereoselective Synthesis of Methyl 9-Methyl-6-oxo-5-tosyl-5,6,6aβ,7β,8,10aβ-hexahydroindenoindole-7α-carboxylate. X-Ray Molecular St...
Cheng, Kin-Fai,Wong, Tze-Tat,Wong, Wing-Tak,Lai, Ting-Fong
, p. 2487 - 2496 (2007/10/02)
The effect of the N-substituents on the polyphosphate ester-(PPE)-catalysed cyclodehydration of a monoester of N-substituted 5-methyl-3-(indol-3'-yl)cyclohex-4-ene-1,2-dicarboxylic acids (41) is presented.Stereoselective synthesis of methyl 9-methyl-6-oxo-5-tosyl-5,6,6aβ,7β,8,10aβ-hexahydroindenoindole-7α-carboxylate (2), the key synthetic intermediate for C(7)-functionalized antifertility agent yuehchukene (YCK) (1) analogues, is dexcribed.
Yuehchukene Analogues
Wenkert, Ernest,Moeller, Peter D. R.,Piettre, Serge R.,McPhail, Andrew T.
, p. 3170 - 3178 (2007/10/02)
Yuehchukene and the bisnoryuehchukenes have been synthesized by the dimerization of β-(dehydroprenyl)indole and its demethyl derivative, respectively.Several routes of preparation of the monomers were developed.These β-indolyl dienes were used in Diels-Al
