114908-47-3

Basic information

• Product Name: C₁₃H₁₄O₅
• CAS NO: 114908-47-3
• Molecular Weight: 250.251
• Mol File: 114908-47-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₃H₁₄O₅(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₃H₁₄O₅(114908-47-3)
• EPA Substance Registry System: C₁₃H₁₄O₅(114908-47-3)

Safety Data

• Hazardous Substances Data: 114908-47-3(Hazardous Substances Data)

Upstream product

• 50-00-0 formaldehyd 
• 3859-41-4 1,3-cyclopentadione 

Relevant articles and documents

Preparation, Reactivity, and Spectral Properties of 1,3-Dioxin Vinylogous Esters: Versatile β-Ketovinyl Cation Equivalents

A full account of the preparation, reactivity, and spectral properties of three 1,3-dioxin vinylogous esters (4-6) is presented.The synthetic approach of these versatile β-ketovinyl cation equivalents involves a BF3*Et2O-promoted Prins reaction between cyclic 1,3-diketones (i.e., 1,3-cyclopentanedione, 1,3-cyclohexanedione, and 1,3-cycloheptanedione) and either formaldehyde or trioxane.The reactions explored include reductive and alkylative 1,3-ketone transpositions, affording a variety of simple β-unsubstituted and β-substituted α-hydroxymethyl α,β-enones, alkylations with carbon electrophiles, and hydroxylations with oxygen electrophiles.