114914-20-4Relevant articles and documents
THE REDUCTION OF 2-VINYL-1,1-BIS(BROMOMETHYL)CYCLOPROPANE
Zefirov, N. S.,Kozhushkov, S. I.,Kuznetsova, T. S.,Sosonkin, I. M.,Domarev,A. M.,et al
, p. 1863 - 1873 (2007/10/02)
A study was carried out on the reduction of 2-vinyl-1,1-bis(bromomethyl)cyclopropane by various methods including electrochemical procedures.The major reaction pathways ential opening and expansion of the cyclopropane ring, while the product of the formation of a second three-membered ring, namely, vinylspiropentane, is formed in low yield.The probable radical mechanism for this reaction is discussed.
MECHANISM OF THE REACTION OF GLYCIDYL ESTERS WITH CARBOXYLIC ACIDS
Klebanov, M. S.,Kir'yazev, F. Yu.,Chervinskii, A. Yu.,Shologon, I. M.
, p. 2193 - 2196 (2007/10/02)
The kinetics of the reactions of 1-phenoxy-2,3-epoxypropane and 2,3-epoxypropylbenzoate with carboxylic acids were investigated.A new reaction mechanism is proposed to explain the anomalously high reactivity of the glycidyl esters.The mechanism involves protonation of the oxygen of the carbonyl group in the ester followed by intramolecular electrophilic attack on the oxirane oxygen by the carbonyl carbon atom, accompanied by opening of the epoxide ring and transfer of the acyl fragment in the glycidyl ester molecule.