1149652-99-2Relevant academic research and scientific papers
Oxidative Addition of X-H (X ) C, N, O) Bonds to [Ir(PMe3) 4]Cl and Catalytic Hydration of Acetonitrile Using its Peroxo Derivative, [Ir(O2)(PMe3)4]Cl, as Catalyst Precursor
Crestani, Marco G.,Steffen, Andreas,Kenwright, Alan M.,Batsanov, Andrei S.,Howard, Judith A. K.,Marder, Todd B.
, p. 2904 - 2914 (2009)
The reactions of [Ir(PMe3)4]Cl (1) with a variety of substrates (acetonitrile, p-aminobenzonitrile, p-cyanophenol) containing a nitrile group were examined. Cleavage of the X-H bonds occurred selectively over the coordination of the
