114969-23-2Relevant academic research and scientific papers
Julia olefination as a general route to phenyl (α-fluoro)vinyl sulfones
He, Maggie,Ghosh, Arun K.,Zajc, Barbara
body text, p. 999 - 1004 (2009/04/04)
Mild and efficient synthesis of phenyl (α-fluoro)vinyl sulfones via condensation of aldehydes and a ketone with a novel benzothiazolyl based bis-sulfone reagent is reported and this proceeds with moderate to good Z-stereoselectivity. Georg Thieme Verlag Stuttgart.
DIETHYL 1-FLUORO-1-PHENYLSULFONYLMETHANEPHOSPHONATE, A VERSATILE AGENT FOR THE PREPARATION OF MONOFLUORINATED BUILDING BLOCKS
Koizumi, Toru,Hagi, Toru,Horie, Yoshiharu,Takeuchi, Yoshio
, p. 3959 - 3962 (2007/10/02)
Diethyl 1-fluoro-1-phenylsulfonylmethanephosphonate was prepared and was transformed into 1-fluoroalkanephosphonate and phenyl 1-fluorovinyl sulfones, which are useful monofluorinated building blocks.KEYWORDS - diethyl 1-fluoro-1-phenylsulfonylmethanephosphonate; 1-fluoroalkanephosphonate; 1-fluorovinyl sulfone; monofluorinated building block; cycloaddition; Michael reaction; Emmons-Horner reaction
