114971-52-7

Basic information

• Product Name: BENZYLTRIMETHYLAMMONIUM DICHLOROIODATE
• Synonyms: BENZYLTRIMETHYLAMMONIUM DICHLOROIODATE;BENZYLTRIMETHYLAMMONIUM DICHLOROIODIDE;BTMA-ICL2;TRIMETHYLBENZYLAMMONIUM DICHLOROIODATE;Benzenemethanaminium, N,N,N-trimethyl-, dichloroiodate(1-);TRIMETHYL BENZYLAMMONIUM DICHLORO IODIDE;Benzyltrimethylammonium dichloroiodide, BTMA-ICl2;Benzyltrimethylammonium dichloroiodate,99%
• CAS NO: 114971-52-7
• Molecular Formula: C10H16Cl2IN
• Molecular Weight: 348.05
• EINECS: -0
• Product Categories: Ammonium Polyhalides, etc. (Quaternary);Halogenation;Iodination;Quaternary Ammonium Compounds;Synthetic Organic Chemistry;Benzothiophenes
• Mol File: 114971-52-7.mol
• Article Data: 6

Chemical Properties

• Melting Point: 124-126 °C(lit.)
• Appearance: Yellow to light brown/Crystalline Powder or Flakes
• Density: 1.5154 (estimate)
• Storage Temp.: Store at 0-5°C
• Solubility: DMSO (Sparingly), Methanol (Slightly)
• Sensitive: Light Sensitive & Hygroscopic
• BRN: 4611949
• CAS DataBase Reference: BENZYLTRIMETHYLAMMONIUM DICHLOROIODATE(CAS DataBase Reference)
• NIST Chemistry Reference: BENZYLTRIMETHYLAMMONIUM DICHLOROIODATE(114971-52-7)
• EPA Substance Registry System: BENZYLTRIMETHYLAMMONIUM DICHLOROIODATE(114971-52-7)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-37/39-36
• WGK Germany: 3
• F: 3
• Hazardous Substances Data: 114971-52-7(Hazardous Substances Data)

Usage

Chemical Properties

Different sources of media describe the Chemical Properties of 114971-52-7 differently. You can refer to the following data:
1. YELLOW TO LIGHT BROWN CRYST. POWDER OR FLAKES
2. Benzyltrimethylammonium dichloroiodate is a slightly brown solid and hygroscopic

Uses

Benzyltrimethylammonium dichloroiodate is used in the mechanism of oxidation.

Health Hazard

Exposures to benzyltrimethylammonium dichloroiodate cause irritation to the eyes, skin, and respiratory tract. Accidental ingestion causes gastrointestinal irritation with nausea, vomiting, and diarrhea. Sparse information on chronic toxicity is available in literature

InChI:InChI=1/C10H16N.Cl2I/c1-11(2,3)9-10-7-5-4-6-8-10;1-3-2/h4-8H,9H2,1-3H3;/q+1;-1

Upstream product

• 121309-88-4 benzyltrimethylazanium tetrachloro-λ³-iodanuide 
• 108-88-3 toluene 
• 56-93-9 benzyltrimethylammonium chloride 

Downstream Products

• 755031-80-2 5-chloro-2-iodo-4-methylaniline 
• 861841-98-7 7-benzyloxy-5-(2-chloro-acetyl)-1H-quinolin-2-one 
• 121309-88-4 benzyltrimethylazanium tetrachloro-λ³-iodanuide 
• 1253795-12-8 (S)-methyl 2-(tert-butoxycarbonylamino)-3-(3-iodo-4-methoxy-5-nitrophenyl)propanoate 
• 284030-62-2 7-Fluoro-6-(4-iodo-2-methyl-phenylamino)-1H-benzoimidazole-5-carboxylic acid methyl ester 

Relevant articles and documents

Light-induced stereospecific intramolecular [2+2]-cycloaddition of atropisomeric 3,4-dihydro-2-pyridones

Atropisomeric 3,4-dihydro-2-pyridones undergo stereospecific [2+2]-photocycloaddition in solution with high stereoselectivity (ee > 98% and de > 96%) in the product. The chiral transfer during phototransformation was rationalized based on the stability/reactivity of the biradical.

Facile Synthesis of Chloro-substituted Aromatic Ethers by Use of Benzyltrimethylammonium Tetrachloroiodate

The reaction of aromatic ethers with a calculated amount of benzyltrimethylammonium tetrachloroiodate in acetic acid (or dichloromethane) under mild conditions gave, selectively, the objective chloro-substituted aromatic ethers in good yields.

α-Chlorination of Aromatic Acetyl Derivatives with Benzyltrimethylammonium Dichloroiodate

Reaction of aromatic acetyl derivatives with benzyltrimethylammonium dichloroiodate in refluxing dichloroethane/methanol for several hours gave α-chloroacetyl derivatives in good yields.