114995-86-7Relevant academic research and scientific papers
New push-pull dyes derived from Michler's ketone for polymerization reactions upon visible lights.
Tehfe, Mohamad-Ali,Dumur, Frederic,Graff, Bernadette,Morlet-Savary, Fabrice,Fouassier, Jean-Pierre,Gigmes, Didier,Lalevee, Jacques
, p. 3761 - 3770 (2013/07/27)
Among other photoinitiating systems, aromatic ketone based compounds have been largely exploited as photoinitiators (PIs). However, none of these compounds efficiently absorb above 420 nm. The search of novel architectures of PIs for getting an important
Thermal Cycloaddition Reactions of ?-Delocalized Singlet Vinylcarbenes: Three-Carbon 1,1-/1,3-Dipoles. The Thermal Three-Carbon + Two-Carbon Cycloaddition
Boger, Dale L.,Wysocki, Ronald J.
, p. 3408 - 3421 (2007/10/02)
Full details of investigations defining new aspects of the scope and mechanism of the three-carbon + two-carbon cycloaddition reaction of ?-delocalized singlet vinylcarbenes (three-carbon 1,1-/1,3-dipoles generated in a reversible, thermal ring opening of cyclopropenone ketals) are detailed.
A Simple and Convenient Synthesis of Aryl-Substituted Push-Pull Butadienes from 1,1-Diaryl-2-propyn-1-ols
Nakatsuji, Shin'inchi,Nakashima, Kenichiro,Iyoda, Masahiko,Akiyama, Shuzo
, p. 2253 - 2255 (2007/10/02)
1,1-Diaryl-2-propyn-1-ol derivatives reacted with several nucleophiles to afford novel 1,1-diarylbutadiene systems.An efficient one-step synthesis of aryl-substituted push-pull butadiene systems was achieved by this reaction.
Reaktion von trans-1-Arylbutadienen und 1,1-Diarylbutadienen mit Tetracyanethylen (TCNE) und 2,2-Bis(trifluormethyl)ethylen-1,1-dicarbonitril (BTF): Kinetische Studie
Drexler, J.,Lindermayer, R.,Hassan, M. A.,Sauer, J.
, p. 2559 - 2562 (2007/10/02)
Kinetic data (substituent effects, solvent effects, activation parameter) are reported for the reactions of trans-1-arylbutadienes 1 and 1,1-diarylbutadienes 3 with TCNE 4 and BTF 5. (2+2)- and (4+2)-cycloadducts 7 respectively 9 can rearrange or undergo cycloreversions with quite different reaction rates depending on the substituent in the aryl-ring.
