115011-59-1

Basic information

• Product Name: Silane, trimethyl[(1E)-1-methyl-3-[(4-methylphenyl)sulfonyl]-1-propenyl]-
• CAS NO: 115011-59-1
• Molecular Formula: C14H22O2SSi
• Molecular Weight: 282.479
• Mol File: 115011-59-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Silane, trimethyl[(1E)-1-methyl-3-[(4-methylphenyl)sulfonyl]-1-propenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, trimethyl[(1E)-1-methyl-3-[(4-methylphenyl)sulfonyl]-1-propenyl]-(115011-59-1)
• EPA Substance Registry System: Silane, trimethyl[(1E)-1-methyl-3-[(4-methylphenyl)sulfonyl]-1-propenyl]-(115011-59-1)

Safety Data

• Hazardous Substances Data: 115011-59-1(Hazardous Substances Data)

Upstream product

• 13411-48-8 1-(trimethylsilyl)ethanone 
• 10439-23-3 4-methylbenzenesulfinyl chloride 
• 75697-67-5 2-trimethylsilyl-3-buten-2-ol 

Downstream Products

• 24931-66-6 2-butenyl p-tolyl sulfone 

Relevant articles and documents

"Syn-Effect" in the Desilylation Reaction of γ-Silylated Allylic and Vinylic Sulfones

The desilylation reaction of γ-silylated allylic sulfones was found to proceed through γ-silylated (E)-vinylic sulfones to afford the corresponding allylic sulfones by treatment with DBU and H2O. The Z/ E ratio of the resulting allylic sulfones varied according to the γ-substituents of the γ-silylated sulfones. This stereo-chemical outcome was rationalized by "syn-effect".