115019-30-2Relevant academic research and scientific papers
Diazo- And transition-metal-free C-H insertion: A direct synthesis of β-lactams
Gomes, Luis F. R.,Veiros, Ls F.,Maulide, Nuno,Afonso, Carlos A. M.
, p. 1449 - 1453 (2015/01/30)
Carbene intermediates are very useful species for a range of reactions including C-H insertions and cycloadditions. They are most commonly generated by metal-catalyzed release of nitrogen gas from diazo precursors. Herein, we present a novel C-H insertion
Construction of β-Lactams by Highly Selective Intramolecular C-H Insertion from Rhodium(II) Carboxylate Catalyzed Reactions of Diazoacetamides
Doyle, Michael P.,Shanklin, Michael S.,Pho, Su-Min Oon Hoan Q.,Heide, Feike R. van der,Veal, William R.
, p. 3384 - 3386 (2007/10/02)
Intramolecular β-C-H insertion occurs in high yield and with exceptional selectivity in rhodium(II) carboxylate catalyzed decompositions of diazoacetamides
