115044-03-6Relevant articles and documents
Isolable phosphaalkenes bearing 2,4,6-trimethoxyphenyl and 2,6-Bis(trifluoromethyl)phenyl as P-substituents
Han, Zeyu,R?hner, David,Samedov, Kerim,Gates, Derek P.
, p. 14643 - 14652 (2020/12/29)
The multistep synthesis and characterization of new P=C analogues of olefins from readily available starting materials is reported. Specifically, the phosphaalkenes TMOP-P=CPh2 (1a: TMOP = 2,4,6-trimethoxyphenyl) and ArF-P=CPh2 [1b: ArF = 2,6-bis(trifluor
2,6-BIS(TRIFLUOROMETHYL)PHENYLPHOSPHINE
Karlstedt, N. B.,Borisenko, A. A.,Foss, V. L.
, p. 1242 - 1245 (2007/10/02)
Reaction of the lithium derivative of 1,3-bis(trifluoromethyl)benzene with phosphorus trichloride yields 2,6-(CF3)2C6H3PCl2, which on reduction gives 2,6-(CF3)2C6H3PH2.The nature of the 2,6-bis(trifluoromethyl)phenyl radical must contribute to stabilizati