115094-15-0

Basic information

• Product Name: Toluene-4-sulfonic acid (5E,7E)-(R)-4-methyl-undeca-5,7-dienyl ester
• Synonyms: Toluene-4-sulfonic acid (5E,7E)-(R)-4-methyl-undeca-5,7-dienyl ester
• CAS NO: 115094-15-0
• Molecular Weight: 336.496
• Mol File: 115094-15-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Toluene-4-sulfonic acid (5E,7E)-(R)-4-methyl-undeca-5,7-dienyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Toluene-4-sulfonic acid (5E,7E)-(R)-4-methyl-undeca-5,7-dienyl ester(115094-15-0)
• EPA Substance Registry System: Toluene-4-sulfonic acid (5E,7E)-(R)-4-methyl-undeca-5,7-dienyl ester(115094-15-0)

Safety Data

• Hazardous Substances Data: 115094-15-0(Hazardous Substances Data)

Upstream product

• 115094-07-0 (R)-2-methyl-(E,E)-4,6-nonadienol 
• 115094-12-7 (5E,7E)-(R)-2-Benzenesulfonyl-4-methyl-undeca-5,7-dienoic acid methyl ester 
• 115094-09-2 Toluene-4-sulfonic acid (3E,5E)-(S)-2-methyl-nona-3,5-dienyl ester 
• 115094-20-7 2-((3E,5E)-(S)-2-Methyl-nona-3,5-dienyloxy)-tetrahydro-pyran 
• 115094-11-6 methyl (R)-4-methyl-(E,E)-5,7-undecadienoate 
• 115094-10-5 (R)-2-methyl-1-iodo-(E,E)-4,6-nonadiene 
• 928-95-0 (E)-2-Hexen-1-ol 
• 115094-14-9 (5E,7E)-(R)-4-Methyl-undeca-5,7-dien-1-ol 
• 98-59-9 p-toluenesulfonyl chloride 

Downstream Products

• 27766-71-8 (-)-8a-epipumiliotoxin c 
• 115094-18-3 (4-Bromo-phenyl)-((2R,4aS,5R)-5-methyl-2-propyl-4a,5,6,7,8,8a-hexahydro-2H-quinolin-1-yl)-methanone 
• 115094-18-3 (4-Bromo-phenyl)-((2S,4aR,5R)-5-methyl-2-propyl-4a,5,6,7,8,8a-hexahydro-2H-quinolin-1-yl)-methanone 

Relevant articles and documents

Octahydroquinoline Syntesis via Immonium Ion Based Diels-Alder Chemistry: Synthesis of (-)-8a-Epipumiliotoxin C

A total synthesis of (-)-8a-epipumiliotoxin C has been developed which features an intramolecular immonium ion based Diels-Alder reaction.Cyclocondensation of the immonium ion 8 derived from optically pure aldehyde 2 and ammonium chloride provided two octahydroquinolines 9 and 10, in a ratio of 2.2:1.The formation of 9 and 10 is rationalized on the basis of the chair-like conformations 16 and 17 respectively.Reduction of the double bond in 9 affored (-)-8a-epipumiliotoxin C.