115148-32-8

Basic information

• Product Name: 2-Oxazolidinone, 4-ethenyl-3-(4-methoxyphenyl)-
• CAS NO: 115148-32-8
• Molecular Formula: C12H13NO3
• Molecular Weight: 219.24
• Mol File: 115148-32-8.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: 2-Oxazolidinone, 4-ethenyl-3-(4-methoxyphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Oxazolidinone, 4-ethenyl-3-(4-methoxyphenyl)-(115148-32-8)
• EPA Substance Registry System: 2-Oxazolidinone, 4-ethenyl-3-(4-methoxyphenyl)-(115148-32-8)

Safety Data

• Hazardous Substances Data: 115148-32-8(Hazardous Substances Data)

Upstream product

• 104-94-9 4-methoxy-aniline 
• 219838-95-6 (Z)-but-2-ene-1,4-bis(ethylcarbonate) 
• 115148-20-4 C₂₀H₂₂N₂O₆ 
• 4427-96-7 4-vinyl-1,3-dioxolan-2-one 
• 5416-93-3 4-Methoxyphenyl isocyanate 
• 451502-80-0 ethyl (2Z)-4-[(p-methoxyanilino)carbonyloxy]-2-butenyl carbonate 

Downstream Products

• 171077-04-6 (+/-)-2-<<(1,1-dimethylethoxy)carbonyl>amino>-3-butenoic acid 
• 169324-82-7 N-tert-butoxycarbonyl-N-(1-hydroxymethyl-2-propenyl)amine 
• 91103-37-6 tert-butyl [(1S)-1-(hydroxymethyl)prop-2-en-1-yl]carbamate 
• 91028-39-6 L-2-<<(tert-Butyloxy)carbonyl>amino>-3-butenoic Acid 

Relevant articles and documents

Palladium-catalyzed enantioselective decarboxylative cycloaddition of vinylethylene carbonates with isocyanates

An efficient method for the enantioselective construction of β-substituted β-vinylglycinol derivatives through palladium-catalyzed decarboxylative cycloaddition of vinylethylene carbonates with isocyanates was developed. By using a palladium complex generated in situ from [Pd2(dba)3] · CHCl3 (dba=dibenzylideneacetone) and (S)-Segphos as a catalyst under mild reaction conditions, the process provided 4-substituted-4-vinyloxazolidin-2-ones in high yields with a high level of enantioselectivity.The stereochemical outcome of the reaction was explained by DFT calculations and the synthetic utility of the process was demonstrated by the gram-scale transformation and formal synthesis of MK-0731 as a kinesin spindle protein inhibitor.

Formal Aza-Wacker Cyclization by Tandem Electrochemical Oxidation and Copper Catalysis

In oxidative electrochemical organic synthesis, radical intermediates are often oxidized to cations on the way to final product formation. Herein, we describe an approach to transform electrochemically generated organic radical intermediates into neutral

Following an ISES lead: The first examples of asymmetric Ni(0)-mediated allylic amination

An ISES (in situ enzymatic screening) lead pointed to conditions (PMP N-protecting group, Ni(cod)2 catalyst precursor) under which chiral, bidentate phosphines could promote Ni(0)-mediated allylic amination. Therefore, bidentate phosphines bear