115148-33-9Relevant articles and documents
Palladium(0)-catalyzed reaction of acidic anilines with (Z)-2-butene- 1,4-diyl dicarbonate - Preparation of N-aryl-4-vinyloxazolidin-2-ones
Moreno-Manas, Marcial,Morral, Lurdes,Pleixats, Roser,Villarroya, Silvia
, p. 181 - 186 (1999)
Palladium-catalyzed reaction of acidic anilines with (Z)-2-butene-1,4- diyl dicarbonate affords N-aryl-4-vinyloxazolidin-2-ones. The success of the reaction depends on the acidity of the aniline and requires in situ conversion of the dicarbonate into carb
Palladium(0)-catalyzed asymmetric cycloaddition of vinyloxiranes with heterocumulenes using chiral phosphine ligands: An effective route to highly enantioselective vinyloxazolidine derivatives
Larksarp, Chitchamai,Alper, Howard
, p. 3709 - 3715 (2007/10/03)
Cycloaddition reaction of 2-vinyloxiranes with carbodiimides using Pd2(dba)3·CHCl3, and TolBINAP as the chiral ligand, in THF at ambient temperature, afforded 4-vinyl-1,3-oxazolidin-2-imines in 70-99% yield and in up to 95