115149-44-5Relevant academic research and scientific papers
Photochemistry of furyl- and thienyldiazomethanes: Spectroscopic characterization of triplet 3-thienylcarbene
Pharr, Caroline R.,Kopff, Laura A.,Bennett, Brian,Reid, Scott A.,McMahon, Robert J.
, p. 6443 - 6454 (2012/05/07)
Photolysis (λ > 543 nm) of 3-thienyldiazomethane (1), matrix isolated in Ar or N2 at 10 K, yields triplet 3-thienylcarbene (13) and α-thial-methylenecyclopropene (9). Carbene 13 was characterized by IR, UV/vis, and EPR spectroscopy. The conform
