1151538-53-2Relevant academic research and scientific papers
2-(p-Tolylsulfinyl)benzyl halides as efficient precursors of optically pure trans-2,3-Disubstituted aziridines
Arroyo, Yolanda,Meana, Angela,Sanz-Tejedor, M. Ascension,Alonso, Ines,Garcia Ruano, Jose Luis
supporting information; experimental part, p. 9874 - 9883 (2010/10/04)
Aziridination of (R)-N-sulfinylaldimines (aryl, heteroaryl and alkenyl derivatives) with 2-(p-tolyl sulfinyl)benzyl iodide in the presence of sodium hexamethyl disilazide takes place with almost complete control of the stereoselectivity (facial and antil
Stereoselective control of planar α-dimethylsulfonium benzyl carbanions. Synthesis of optically pure trans-aziridines
Arroyo, Yolanda,Meana, Angela,Rodriguez, J. Felix,Sanz-Tejedor, M. Ascension,Alonso, Ines,Ruano, Jose L. Garcia
experimental part, p. 4217 - 4224 (2009/09/25)
(Chemical Equation Presented) (R)-N-Sulfinylimine and (S)-N-sulfinylimine react with the ylide derived from (S)-dimethyl-[2-(p-toluenesulfinyl) phenyl]sulfonium salt, affording trans-2,3-disubstituted aziridines. A complete trans selectivity in low facial
