115167-60-7Relevant academic research and scientific papers
In(OTf)3-Catalyzed Friedel-Crafts Reaction of Aromatic Compounds with Methyl Trifluoropyruvate in Water
Ding, Rui,Zhang, Hai Bo,Chen, Yong Jun,Liu, Li,Wang, Dong,Li, Chao Jun
, p. 555 - 557 (2004)
In the presence of In(OTf)3 as a catalyst, aniline derivatives 1a-c, 1e-h and anisole derivatives 2a-c, 2e reacted with methyl trifluoropyruvate 3 in water at room temperature to give the corresponding Friedel-Crafts reaction products 4a-g and
Friedel-Crafts reactions catalyzed by samarium diiodide
Soueidan, Mohamad,Collin, Jacqueline,Gil, Richard
, p. 5467 - 5470 (2007/10/03)
Samarium diiodide is an efficient precatalyst for the Friedel-Crafts reaction involving various aromatic substrates and chelating electrophiles. Alkyl 3,3,3-trifluoropyruvates are transformed into α-hydroxyesters in good yields with total regioselectivity
