115171-19-2Relevant academic research and scientific papers
Crystal Structure of a 1:1 Inclusion Complex of (R,R)-(-)-1,6-Bis(o-chlorophenyl)-1,6-diphenylhexa-2,4-diyne-1,6-diol and (-)-(Z)-Benzylidene-2-(3-methylbutyl)azane Oxide
Toda, Fumio,Tanaka, Koichi,Mak, Thomas C. W.
, p. 1329 - 1330 (1989)
Crystal structure analysis of the title complex establishes the chirality of the (-)-(Z)-nitrone and the path of its photocyclization to the corresponding optically active oxaziridine.
SELECTIVE REACTIONS IN THE SOLID STATE AND ORGANIC SOLID-SOLID REACTIONS
Toda, Fumio
, p. 41 - 48 (2007/10/02)
Since guest molecules in a host-guest complex are arranged regularly and are packed closely, reaction of the guest in the complex is expected to proceed selectively and efficiently in the solid state.When the host compound is chiral, reaction of the guest would proceed enantioselectively.Some such reactions were studied.Furthermore, some usual organic reactions were found to proceed in the solid state.In some cases, organic solid state reactions proceeded more selectively and much faster than in solution.Such solid-solid reactions were also investigated.
Enantioselective Photocyclization of Nitrones into Oxaridines in a Crystalline Inclusion Complex with Optically Active 1,6-Di(o-chlorophenyl)-1,6-diphenylhexa-2,4-diyne-1,6-diol
Toda, Fumio,Tanaka, Koichi
, p. 2283 - 2284 (2007/10/02)
Irradiation of complexes of nitrones with the title host compound in the solid state gave optically active oxaziridines in 100percent enantiomeric excess.
