1151899-28-3Relevant academic research and scientific papers
A phenacrylate scaffold for tunable thiol activation and release
Sankar, Rathinam K.,Kumbhare, Rohan S.,Dharmaraja, Allimuthu T.,Chakrapani, Harinath
supporting information, p. 15323 - 15326 (2015/01/09)
A thiol-selective 2-methyl-3-phenacrylate scaffold with spatiotemporal control over delivery of a cargo is reported. The half-lives of decomposition could be tuned from 30 min to 1 day and the scaffold's utility in thiol-inducible fluorophore release in cell-free as well as within cells is demonstrated.
Novel synthesis of (E)-3-arylidene-2,3-dihydrobenzo[b][1,4]oxazepin-4(5H)- ones using Baylis-Hillman derivatives via reductive cyclization
Bakthadoss, Manickam,Murugan, Gandhi
experimental part, p. 1290 - 1298 (2009/09/25)
A simple synthesis of novel (E)-3-arylidene-2,3-dihydrobenzo[b][1,4] oxazepin-4(5H)-ones from bromides of the Baylis - Hillman adducts using Fe/AcOH for the in situ reduction of nitro group, into an amino group, followed by the cyclization as a key step,
