1152172-64-9Relevant academic research and scientific papers
Platinum(II) catalysts for highly enantioselective 1,6-enyne cycloisomerizations. Synthetic, structural, and catalytic studies
Brissy, Delphine,Skander, Myriem,Jullien, Helene,Retailleau, Pascal,Marinetti, Angela
, p. 2137 - 2139 (2009)
A new family of cyclometalated (N-heterocyclic carbene)-Ptll complexes bearing monodentate phosphines as ancillary ligands has been designed for use as precatalysts In 1,6-enyne cyclolsomerlzatlon reactions. Highly enantioselective skeletal rea
Cyclometalated N-heterocyclic carbene-platinum catalysts for the enantioselective cycloisomerization of nitrogen-tethered 1,6-enynes
Jullien, Helene,Brissy, Delphine,Sylvain, Remy,Retailleau, Pascal,Naubron, Jean-Valere,Gladiali, Serafino,Marinetti, Angela
experimental part, p. 1109 - 1124 (2011/07/09)
Platinum(II) complexes which combine six-membered N-heterocyclic carbene-containing metallacyclic units and monodentate chiral phosphines have been prepared. The key step of their synthesis is the intramolecular oxidative addition of N-2-iodobenzylimidazo
