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115219-49-3

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115219-49-3 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 115219-49-3 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,1,5,2,1 and 9 respectively; the second part has 2 digits, 4 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 115219-49:
(8*1)+(7*1)+(6*5)+(5*2)+(4*1)+(3*9)+(2*4)+(1*9)=103
103 % 10 = 3
So 115219-49-3 is a valid CAS Registry Number.

115219-49-3Upstream product

115219-49-3Downstream Products

115219-49-3Relevant articles and documents

Photochemical Reactions of 4-Acylstyrenes. Effects of Acyl Substituents on Photocyclodimerization via an Excited Triplet State

Tsubakiyama, Kyoji,Miyagawa, Kohji,Kaizaki, Kiyotaka,Yamamoto, Masahide,Nishijima, Yasunori

, p. 837 - 845 (1992)

The photochemical reactions of 4-acylstyrenes (1a-e; acyl=acetyl, benzoyl, 1-naphthoyl, 2-naphthoyl, and 9-phenanthrylcarbonyl, respectively) were investigated, and their excited state behavior and photoreactivities are discussed in relation to the aryl ketone structures.Photoirradiation of 1a-e in benzene gave two isomeric cyclodimers of trans- and cis-1,2-bis(4-acylphenyl)cyclobutanes (2a-e and 3a-e) as main products, accompanied by the formation of some oligomers and polymers.The fractions of the trans-form in the cyclodimers were ca. 80percent; this indicated that the cyclodimerization proceeded via the ?,?* triplet state.The quantum yields of the photodimerization for 1a-e were almost the same irrespective of the acyl substituents (Φ=0.03-0.04 at =0.1 mol dm-3).Phosphorescence spectra of 1c (τ=0.48 s) and 1d (τ=0.91 s) observed in a rigid solution at 77 K, which coincided with those of the respective model aryl ketones, were ascribed to the low-lying excited ?,?* triplet states localized on the naphthalene moiety of the molecules.Phosphorescence emissions of 1a and 1b could not be detected.The transient absorption spectrum of 1d (τ=23 ns) observed in a fluid solution at 293 K was tentatively assigned to the ?,?* triplet state mainly localized on the styrene moiety of the molecule.The photoreaction mechanism is discussed in terms of the intramolecular triplet energy transfer.

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