1152306-47-2Relevant academic research and scientific papers
Palladium-catalyzed cross-couplings of 1,3-butadien-2-yl species with organoindiums generated from allenylmethyl bromide and indium
Kim, Sundae,Seomoon, Dong,Lee, Phil Ho
supporting information; experimental part, p. 1873 - 1875 (2009/10/17)
An organoindium generated from the reaction of indium with allenylmethyl bromide is an efficient nucleophile in Pd-catalyzed cross-couplings, producing 1,3-butadienes; cross-couplings followed by [4 + 2] cycloadditions gave six-membered carbocycles in a o
Palladium-catalyzed 1-methylene-2-propenylation reactions of aryl bromides with 3,4-alkadien-1-ols via carbon-carbon bond cleavage for the synthesis of 2-aryl-1,3-butadiene derivatives
Imoto, Junichi,Hayashi, Sayuri,Hirano, Koji,Yorimitsu, Hideki,Oshima, Koichiro
experimental part, p. 393 - 400 (2009/06/28)
A method for the synthesis of 2-aryl-1,3-alkadienes has been developed. Treatment of aryl bromides with 3,4-alkadien-1-ols in the presence of a palladium catalyst results in 1-methylene-2-propenyl group transfer to aryl bromides. Taking advantage of palla
