1152491-46-7Relevant academic research and scientific papers
Silylene and germylene intermediates in the reactions of silole and germole dianions with N,N′-Di-tert-butylethylenediimine
Toulokhonova, Irina S.,Timokhin, Vitaly I.,Bunck, David N.,Guzei, Ilia,West, Robert,Mueller, Thomas
experimental part, p. 2344 - 2349 (2009/03/11)
Spiro-diazasilole (germole) adducts were observed in reactions of dilithium salts of silole and germole dianions with N,N′-di-tert- butylethylenediimine in THF at room temperature. A proposed mechanism of the reaction includes metallation of N,N′-di-tert-butylethylenediimine and the formation of an intermediate silylene or germylene. This reaction mechanism was supported by experimental data and theoretical calculations. Wiley-VCH Verlag GmbH & Co. KGaA, 2008.
