115260-29-2

Upstream product

• 13039-67-3 (2S,3S,4S)-2-(hydroxymethyl)-5-methoxyoxolane-3,4-diol 
• 100-44-7 benzyl chloride 
• 51587-94-1 methyl 3,5-O-benzylidene-β-D-xylofuranoside 

Downstream Products

• 80229-18-1 methyl 2,5-di-O-benzyl-β-D-xylofuranoside 
• 115260-33-8 methyl 2,5-di-O-benzyl-3-O-methyl-α-L-xylofuranoside 
• 115260-31-6 methyl 2,5-di-O-benzyl-α-L-xylofuranoside 

Relevant academic research and scientific papers

HYDROGENOLYSIS OF DIOXANE-TYPE BENZYLIDENE ACETALS FUSED TO FURANOSIDE RINGS. SYNTHESIS OF 3-O-METHYL-L-XYLOSE

Methyl 2-O-benzyl-3,5-O-benzylidene-α-L-xylofuranoside (4) and methyl 2-O-benzyl-3,5-O-benzylidene-β-L-xylofuranoside (5) were hydrogenolysed with LiAlH4-AlCl3 reagent to obtain the 2,5-di-O-benzyl ethers (6 and 7).Compounds 6 and 7 were methylated and th

HYDROGENOLYSIS OF 3,5-O-BENZYLIDENE ACETALS WITH THE LiAlH4-AlCl3 REAGENT IN METHYL D-XYLOFURANOSIDES

The hydrogenolysis of methyl 3,5-O-benzylidene-α- and -β-D-xylofuranoside derivatives with the LiAlH4-AlCl3 reagent gave 5-benzyl ethers as main products.In some cases the attack of the reagent occured at the ring oxygen of the furanoside skeleton to yiel