115268-53-6Relevant academic research and scientific papers
Bicyclononynes
Antony-Mayer, Christina,Meier, Herbert
, p. 2013 - 2018 (2015/08/27)
MNDO calculations reveal that two diastereomeric conformations a and b of low energy exist for each of the three isomeric cis-bicyclononynes (1-3).For the experimental proof, the highly strained bicyclic systems, generated by the selenadiazole method or by dehydrobromination, are investigated by 1H- and 13C-NMR measurements concerning the population of the conformers and their mutual interconversion by inversion of the eight-membered rings.
