115270-12-7

Basic information

• Product Name: Carbamic acid, 2,4-hexadienyl-, 1,1-dimethylethyl ester, (E,E)- (9CI)
• Synonyms: Carbamic acid, 2,4-hexadienyl-, 1,1-dimethylethyl ester, (E,E)- (9CI)
• CAS NO: 115270-12-7
• Molecular Formula: C11H19NO2
• Molecular Weight: 197.27406
• Product Categories: N-BOC
• Mol File: 115270-12-7.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Carbamic acid, 2,4-hexadienyl-, 1,1-dimethylethyl ester, (E,E)- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Carbamic acid, 2,4-hexadienyl-, 1,1-dimethylethyl ester, (E,E)- (9CI)(115270-12-7)
• EPA Substance Registry System: Carbamic acid, 2,4-hexadienyl-, 1,1-dimethylethyl ester, (E,E)- (9CI)(115270-12-7)

Safety Data

• Hazardous Substances Data: 115270-12-7(Hazardous Substances Data)

Upstream product

• 57006-69-6 (E,E)-sorbyl acetate 
• 51779-32-9 iminodicarboxylic acid di-tert-butyl ester 
• 17102-64-6 Sorbyl alcohol 
• 216959-34-1 ethyl 2-{[(tert-butoxy)carbonyl]amino}-2-oxoacetate 
• 872672-18-9 tert-butyl ((2E,4E)-hexa-2,4-dien-1-yl) carbonate 
• 4248-19-5 tert-butyl carbazate 

Relevant articles and documents

N-Methyl Allylic Amines from Allylic Alcohols by Mitsunobu Substitution Using N-Boc Ethyl Oxamate

We report the practical, scalable synthesis of a range of N-methyl allylic amines. Primary and secondary allylic alcohols underwent a regioselective Mitsunobu reaction with readily accessible N-Boc ethyl oxamate to deliver the corresponding N-Boc allylic amines, including in enantiopure form via stereospecific substitution. Subsequent N-methylation and Boc deprotection without chromatography yielded the amine products as hydrochloride salts. This method solves the problem of converting commercially available alcohols into often volatile N-methyl allylic amines, many of which have limited commercial availability.

An Efficient, Palladium-Catalyzed Route to Protected Allylic Amines

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