115289-51-5Relevant academic research and scientific papers
Metal Complexes with Biologically Important Ligands, XLVII. - Copper, Nickel, Palladium, and Platinum(II) Complexes of C-Allylglycine and N-(Diphenylmethylene)-C-allylglycine Ester
Steiner, Norbert,Nagel, Ulrich,Beck, Wolfgang
, p. 1759 - 1766 (2007/10/02)
C-Allylglycine reacts with Ni, Cu, Pd, and Pt(II) salts - dependent on pH - to give trans-N,O-bischelate complexes M2 (M = Cu, Ni, Pd) 1 or N,ν2-C,C-chelate complexes Cl2MNH2CH(CO2R)CH2CR=CH2 ( R = H, Me; M = Pd, Pt).The reactions of N-(diphenylmethylene)-C-allylglycine ester with Na2PdCl2 and PtCl2 yield ortho-metallated complexes 3, in which the ligand is bound to the ortho-C(phenyl) atom, the imino-N atom, and the olefinic double bond. 2a and 3c were characterized by X-ray structure analyses.
